Enhancement of Oxygen Reduction Reaction Catalytic Activity via the Modified Surface of La0.6Sr0.4Co0.2Fe0.8O3−δwith Palladium Nanoparticles as Cathode for Lithium–Air Battery
2018 · ACS Applied Energy Materials
저자
Mi Young Oh, Sung Kwan Park, Hyeokjun Park, Hanbit Kim, 강기석 (Kisuk Kang), Jung Hyun Kim, Kwang Chul Roh, Tae Ho Shin
연구주제
Electrocatalysts for Energy Conversion · Advanced Battery Materials and Technologies · Advancements in Battery Materials
NTIS 과학기술표준분류
에너지/자원만에너지·환경·원자력 확장
가장 가까운 분류(재료 > 금속재료 > 에너지소재기술)가 에너지·환경·원자력 확장 범위 밖이다.
AI 연구 키워드·방법
리튬-산소 전지(리튬-공기 전지) 산소 환원 반응(ORR) palladium nanoparticle 페로브스카이트 산화물 전기촉매
키워드 (OpenAlex)
oxygen reduction reaction lithium-oxygen batteries La0.6Sr0.4Co0.2Fe0.8O3-δ perovskite oxides palladium nanoparticles bifunctional catalysts cathode materials surface modification
초록
La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ (LSCF) perovskites have previously emerged as efficient cathode catalysts for various electrochemical devices such as solid oxide fuel cells, due to their superior chemical stability and mixed electron–ion conductivity. Recently, LSCFs have been studied as the cathode of lithium–air batteries at low temperature due to superior electrocatalytic activity. In the case of low-temperature applications, LSCF exhibits low catalytic activity for the oxygen reduction reaction (ORR), despite its relatively good activity for the oxygen evolution reaction (OER). However, the activity on ORR is still a barrier to LSCF being utilized as a catalyst for low-temperature electrochemical devices such as lithium–air battery. In this work, different palladium (Pd) contents were deposited on the LSCF surface to improve its ORR activity as a promising bifunctional catalyst in …
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Electrocatalysts for Energy Conversion