Rapid Flame-Annealed CuFe2O4 as Efficient Photocathode for Photoelectrochemical Hydrogen Production

Copper ferrite (CuFe 2 O 4 ) possesses an indirect bandgap in the range of 1.54–1.95 eV. It is used as an attractive p -type photocathode in photoelectrochemical (PEC) water splitting, and theoretically it can yield a maximum photocurrent density of ∼27 mA/cm 2 and a maximum solar-to-hydrogen conversion efficiency of ∼33%. To date, only a few reports have been published on CuFe 2 O 4 photocathodes with very low-photocurrent densities, with a maximum value of 0.4 mA/cm 2 at 0.4 V vs RHE. Herein, we prepared a CuFe 2 O 4 photocathode on FTO glass with the sol–gel method followed by either high-temperature flame annealing or furnace annealing. We found that the flame-annealed CuFe 2 O 4 photocathode generated a photocurrent density of 1.82 mA/cm 2 at 0.4 V vs RHE that is approximately 3.5 times higher than the furnace-annealed CuFe 2 O 4 (0.52 mA/cm 2 ). This photocurrent density is also hi…