Tunable Redox-Active Triazenyl–Carbene Platforms: A New Class of Anolytes for Non-Aqueous Organic Redox Flow Batteries

Non-aqueous all organic redox flow batteries (NORFBs) are one of the promising options for large-scale renewable energy storage systems owing to their scalability with energy and power along with the affordability. The discovery of new redox-active organic molecules (ROMs) for the anolyte/catholyte would bring them one step closer to the practical application, thus it is highly demanded. Here, we report a new class of ROMs based on cationic triazenyl systems supported by N -heterocyclic carbenes (NHCs) and demonstrate, for the first time, that the triazenyl can serve as a new redox motif for ROMs and could be significantly stabilized for the use in NORFBs by the coupling with NHCs even at radical states. A series of NHC–triazenyl ROM families were successfully synthesized via the reaction of a synthon, N -heterocyclic carbene azido cation, with various Lewis bases including NHCs. Remarka…