Zirconium metal recovery from irradiated radioactive zirconium alloy via c hloride‐based electrorefining and thermal decomposition of ZrCl

Chloride salt–based decontamination methods for neutron-irradiated radioactive zirconium alloys have been designed to directly recover metallic Zr. Previous studies have shown that ZrCl is co-deposited with Zr at a low current density on the cathode, while sparse and low-purity Zr is obtained with the application of a high current density. We propose a process to prepare high-purity Zr metal involving the electrochemical recovery of ZrCl and thermal decomposition of ZrCl to Zr. Electrodeposition of ZrCl in a LiCl-KCl-ZrCl4 system by controlling the cathode potential at −1.1 V (vs Ag/AgCl, −2.3 V vs Cl2/Cl−) was performed at 723 K to produce ZrCl and confirm the morphology of deposition. Dense and layered depositions adhered to the cathode were introduced to a vacuum distillation furnace after washing with pyridine solvent. The optimized condition of the thermal decomposition process was …