Flexible and Thermally Stable ATRP-Modified Lignin/PEO Composite Membrane

To utilize lignin, which is a sustainable natural polymer, a star-like lignin- graft -polyethylene glycol methacrylate–glycidyl methacrylate (LGPG) polymer was prepared via solvent extraction and atom transfer radical polymerization (ATRP). Ethyl acetate-extracted lignin, obtained from the solvent extraction of Kraft lignin (KL), exhibited higher reactivity in ATRP, resulting in the synthesis of a star-like structure with a higher degree of polymerization than KL. The resulting LGPG/poly(ethylene oxide) (PEO) composite membranes exhibited high thermal stability and excellent elongation at break of 598.56% (with 0.3 g of LGPG). These findings indicated that LGPG imparted more flexible properties to the membranes than those made solely of PEO. Moreover, the addition of LGPG to the composite membrane decreased the glass transition temperature and crystallinity. These results indicated a pla…