Spatiotemporal inhomogeneity of total column NO2 in a polluted urban area inferred from TROPOMI and Pandora intercomparisons

The spatiotemporal inhomogeneity of the total column NO2 amounts (TCN) in the Seoul Metropolitan Area (SMA), Korea, was quantitatively assessed through year-round (October 2019–May 2021) TROPOMI and ground-based Pandora measurements. The average TCN over the SMA was comparable to that of major Chinese megacities, being consistently high (> 0.8 DU; Dobson Unit) during the daytime (10–17 local standard time). The autocorrelation scores of the Pandora-measured TCNs demonstrated high temporal variability attributed to the spatial inhomogeneity of NO2 emissions within the SMA and near-surface advection. Accordingly, the adequate temporal collocation range for Pandora measurements for the intercomparison with the satellite sensors was considered to be ± 5 min to avoid significant uncertainty from the temporal variability (RMSE < 0.1 DU, R2 > 0.96). TROPOMI showed better agreement with conventi…