Nature-derived hydrogel for microplastic removal

Abstract The accumulation of microplastics in aquatic environments poses a significant threat to ecosystems and human health. In response, we developed a sustainable and bio-based adsorbent hydrogel composed of chitin and cationic lignin for efficient removal of nanoplastics from wastewater. The composite hydrogel exhibited excellent mechanical integrity in aqueous media and fully recovered its structure after mechanical deformation, ensuring durability during operation. Importantly, adsorption experiments were conducted under neutral pH conditions to reflect realistic aquatic environments, and the hydrogel achieved a maximum adsorption capacity of 1,790.8 mg/g—substantially surpassing the performance of previously reported nanoplastic adsorbents. Adsorption kinetics followed the pseudo-second-order model, while the isotherm behavior followed the Langmuir model. The removal mechanism was…